1.
1.85 g sample of an arsenic-containing pesticide was chemically converted to AsO43\text{AsO}_4^{3-} (atomic mass of As = 74.9) and titrated with Pb2+\text{Pb}^{2+} to form Pb3(AsO4)2\text{Pb}_3(\text{AsO}_4)_2. If 20 mL of 0.1 M Pb2+\text{Pb}^{2+} is required to reach the equivalence point, the mass percentage of arsenic in the pesticide sample is closest to