1.
For the first-order reaction AB\text{A} \rightarrow \text{B}, A\text{A} is optically active and B\text{B} is optically inactive. A series of experiments were conducted on a solution of A\text{A}:

| Time (min.) | 00 | 6060 | \infty |
|---|---|---|---|
| Optical rotation | 82°82° | 77°77° | 2° |

Assume some impurity is present. Calculate the optical rotation after 5hours5\,\text{hours}. (Given ln1.066=0.064\ln 1.066 = 0.064, e0.16=1.17e^{0.16} = 1.17)