1.
The mass of Na3PO4\mathrm{Na_3PO_4} that should be added to 10L10\,\mathrm{L} of 1.0×105M1.0 \times 10^{-5}\,\mathrm{M} BaCl2\mathrm{BaCl_2} solution without any precipitation of Ba3(PO4)2\mathrm{Ba_3(PO_4)_2} is [KspK_{sp} of Ba3(PO4)2=4×1023\mathrm{Ba_3(PO_4)_2} = 4 \times 10^{-23}]