1.
The rate of decomposition for methyl nitrite and ethyl nitrite can be given in terms of rate constant k1k_1 and k2k_2 respectively. The energy of activation for the two reactions are 152.30 kJ mol1^{-1} and 157.7 kJ mol1^{-1} as well as frequency factors are 101310^{13} and 101410^{14} respectively for the decomposition of methyl and ethyl nitrite. Calculate the temperature at which rate constant will be same for the two reactions.