1.
For Cr2_2O72_7^{2-} + 14H+^+ + 6e^- \rightarrow 2Cr3+^{3+} + 7H2_2O; E^\circ = 1.33 V. At [Cr2_2O72_7^{2-}] = 4.5 millimole, [Cr3+^{3+}] = 15 millimole, E is 1.067 V. The pH of the solution is nearly equal to