1.
Using the Gibbs energy change, ΔG∘=+63.3\Delta G^\circ = +63.3 kJ, for the following reaction, Ag2_2CO3→2_3 \rightarrow 2Ag+^+(aq) + CO32−_3^{2-}(aq), the KspK_{sp} of Ag2_2CO3_3(s) in water at 25∘^\circC is (R=8.314R = 8.314 J K−1^{-1} mol−1^{-1}, given 100.91≅810^{0.91} \cong 8):