1.
5.1 g5.1\,\text{g} NH4SH\mathrm{NH_4SH} is introduced in a 3.0 L3.0\,\text{L} evacuated flask at 327∘C327^{\circ}\mathrm{C}. 30%30\% of the solid NH4SH\mathrm{NH_4SH} decomposes to NH3\mathrm{NH_3} and H2S\mathrm{H_2S} as gases. The KpK_p of the reaction at 327∘C327^{\circ}\mathrm{C} is (R=0.082 L atm mol−1K−1R = 0.082\,\text{L atm mol}^{-1}\text{K}^{-1}, molar mass of S =32 g mol−1= 32\,\text{g mol}^{-1}, molar mass of N =14 g mol−1= 14\,\text{g mol}^{-1}):