1.
In qualitative analysis, the metals of group I can be separated from other ions by precipitating them as chloride salts. A solution initially contains Ag+Ag^+ and Pb2+Pb^{2+} at a concentration of 0.10 M. Aqueous HCl is added to this solution until the ClCl^- concentration is 0.10 M. What will the concentrations of Ag+Ag^+ and Pb2+Pb^{2+} be at equilibrium? (KspK_{sp} for AgCl = 1.8×10101.8 \times 10^{-10}, KspK_{sp} for PbCl2PbCl_2 = 1.7×1051.7 \times 10^{-5})