1.
The bond dissociation energy of B−FB-F in BF3BF_3 is 646 kJ mol−1646\,kJ\,mol^{-1} whereas that of C−FC-F in CF4CF_4 is 515 kJ mol−1515\,kJ\,mol^{-1}. The correct reason for higher B−FB-F bond dissociation energy as compared to that of C−FC-F is: