1.
For the gaseous reactions (I) and (II), the equilibrium constants are XX and YY respectively.

(I) 12N2(g)+O2(g)NO2(g)\frac{1}{2}\text{N}_2(g) + \text{O}_2(g) \rightleftharpoons \text{NO}_2(g)

(II) 2NO2(g)N2O4(g)2\text{NO}_2(g) \rightleftharpoons \text{N}_2\text{O}_4(g)

Using the above reactions, the equilibrium constant ZZ for the reaction (III) given below is

(III) N2O4(g)N2(g)+2O2(g)\text{N}_2\text{O}_4(g) \rightleftharpoons \text{N}_2(g) + 2\text{O}_2(g)