1.
If the equilibrium constants of the following equilibria SO2+12O2SO3\mathrm{SO_2 + \frac{1}{2}O_2 \rightleftharpoons SO_3} and 2SO32SO2+O2\mathrm{2SO_3 \rightleftharpoons 2SO_2 + O_2} are given by K1_1 and K2_2 respectively, which of the following relations is correct?