1.
Which of the following reaction(s) can be used for the preparation of alkyl halides?

(I) CH3_3CH2_2OH + HCl
(II) CH3_3CH2_2OH + HCl \rightarrow
(III) (CH3_3)3_3COH + HCl \rightarrow
(IV) (CH3_3)2_2CHOH + HCl (Anhyd. ZnCl2_2)