1.
In a vessel, O2\mathrm{O_2} gas undergoes physisorption on an adsorbent surface, causing its partial pressure to decrease from 6atm6\,\text{atm} to PatmP\,\text{atm} in an 8.21L8.21\,\text{L} vessel at 500K500\,\text{K}. If the total number of sites on the adsorbent surface is 2×10232 \times 10^{23} and every site accommodates effectively three O2\mathrm{O_2} molecules, find PP (in atm). [NA=6×1023N_A = 6 \times 10^{23}]