1.
Solid Na2_2SO4_4 is slowly added to a solution which is 0.020 M in Ba(NO3_3)2_2 and 0.020 M in Pb(NO3_3)2_2. Assume no increase in volume. Preferential precipitation takes place. What is the concentration of Ba2+^{2+} when PbSO4_4 starts to precipitate? Ksp(BaSO4)=1.0×1010K_{sp}(\text{BaSO}_4) = 1.0 \times 10^{-10} and Ksp(PbSO4)=1.6×108K_{sp}(\text{PbSO}_4) = 1.6 \times 10^{-8}